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thiazyl trifluoride : ウィキペディア英語版
thiazyl trifluoride

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Thiazyl trifluoride is a chemical compound of nitrogen, sulfur, and fluorine, having the formula NSF3. It exists as a stable, colourless gas, and is an important precursor to other sulfur-nitrogen-fluorine compounds. It has tetrahedral molecular geometry around the sulfur atom, and is regarded to be a prime example of a compound that has a sulfur-nitrogen triple bond.
==Preparation==
NSF3 can be synthesised by the fluorination of thiazyl fluoride, NSF, with silver(II) fluoride, AgF2:
:NSF + 2 AgF2 → NSF3 + 2 AgF
or by the oxidative decomposition of FC(O)NSF2 by silver(II) fluoride.:
:FC(O)NSF2 + 2 AgF2 → NSF3 + 2 AgF + COF2
It is also a product of the oxidation of ammonia by .

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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